Trans-ethyl methyl ether in space A new look at a complex molecule in selected hot core regions
نویسنده
چکیده
An extensive search for the complex molecule trans-ethyl methyl ether towards several hot core regions has been performed. Using the IRAM 30m telescope and the SEST 15m we looked at several frequencies where trans-ethyl methyl ether has strong transitions, as well as lines which are particularly sensitive to the physical conditions in which the molecule can be found. We included G34.26, NGC6334(I), Orion KL, and W51e2 which have previously been proven to have a rich chemistry of complex molecules. Our observations cannot confirm the tentative Orion KL detection made by Charnley et al.(2001) within their stated column density limits, but we confirm the existence of the trans-ethyl methyl ether towards W51e2 with a column density of 2 × 10 cm. The dimethyl ether/methanol ratio of 0.6 as well as the newly found ethyl methyl ether/ethanol ratio of 0.13 indicate relative high abundances of ethers toward W51e2. Furthermore, the observation of ethyl methyl ether also confirms the importance of ethanol as a grain mantle constituent. We present new upper limits of around 8×10 cm for the column densities of the molecule toward Orion KL, G34.26, NGC6334(I) and estimate the column density towards SgrB2(N) to be of the same order. The W51e2 observations are discussed in more detail.
منابع مشابه
Searching for trans ethyl methyl ether in Orion KL.
We report on the tentative detection of trans ethyl methyl ether (tEME), t-CH3CH2OCH3, through the identification of a large number of rotational lines from each one of the spin states of the molecule towards Orion KL. We also search for gauche-trans-n-propanol, Gt-n-CH3CH2CH2OH, an isomer of tEME in the same source. We have identified lines of both species in the IRAM 30 m line survey and in t...
متن کاملCCSD(T) study of the far-infrared spectrum of ethyl methyl ether.
Band positions and intensities for the far-infrared bands of ethyl methyl ether are variationally determined from a three-dimensional (3D) potential energy surface calculated with CCSD(T)/cc-pVTZ theory. For this purpose, the energies of 181 selected geometries computed optimizing 3n-9 parameters are fitted to a 3D Fourier series depending on three torsional coordinates. The zero point vibratio...
متن کاملOptimization of Biodiesel Production by Chemical Trans-esterification of Sunflower Oil
Vegetable oils and fats in comparison with diesel fuel have high viscosity, by transesterification method the viscosity of oil can be decreased. Transesterification of triglyceride with alcohol is one of the methods for production of biodiesel. In this study sunflower oil, methanol and ethanol, with molar ratio of (1:3, 1:4, 1:6, 1:8) and temperature (40, 50, 60 º C) were dependent parameters e...
متن کاملSYNTHESIS, X-RAY CRYSTAL STRUCTURE AND IR STUDY OF NEW TRINUCLEAR, BASE CARBOXSYLATE COMPLEX OF [Cu3O(OAc)6(H2O)3]Cl.CH3OH.6H2O
The synthesis of [Cu3O(OAc)6(H2O)3]Cl.CH3OH.6H2O is described. The X-ray crystallographic study of thecomplex revealed an isosceles triangle of copper atoms with a triply bridging oxo atom nearly in the plane of thetriangle. The coordination sphere around each metal center is close to distorted octahedral and the central{Cu3(μ3-O)} core is planar. Every two copper atoms were connected to each o...
متن کاملHigh Resolution Λ=1mm Carma Observations of Large Molecules in Orion-kl
We present high resolution, Combined Array for Research in Millimeter-Wave Astronomy (CARMA), λ=1mm observations of several molecular species toward Orion-KL. These are the highest spatial and spectral resolution 1mm observations of these molecules to date. Our observations show that ethyl cyanide [C2H5CN] and vinyl cyanide [C2H3CN] originate from multiple cores near the Orion hot core and IRc7...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره شماره
صفحات -
تاریخ انتشار 2005